Target Audience: Procurement Engineers, Plant Managers, and PU Formulation Specialists in Saudi Arabia and the GCC region.
Key Entities & CAS: Polymeric MDI (CAS 9016-87-9 | UN 2078 Class 6.1), Rigid Polyether/Polyester Polyols (CAS 9003-11-6 / 25322-69-4), Wannate PM200, Wannate PM400.
Target Ports: Dammam (King Abdulaziz Port), Jeddah Islamic Port, Riyadh Dry Port.
Target Keywords: Polymeric MDI Saudi Arabia, PM200 bulk supplier Dammam, Rigid polyether polyol PIR panel Jeddah, PMDI ISO Tank CIF Dammam, Polyurethane insulation raw materials China supplier.
Quick Summary for Procurement & Process Engineers
Sourcing Polymeric MDI (PMDI / Wanhua Wannate PM200, CAS 9016-87-9) and sucrose/glycerin-initiated rigid polyether polyols from Ningbo Port, China to Saudi Arabia (King Abdulaziz Port in Dammam and Jeddah Islamic Port) typically takes about 18 to 22 days via direct container vessel, depending on carrier and sailing schedule. For PIR (Polyisocyanurate) and PUR (Polyurethane) continuous sandwich panel production in Saudi Arabia's high ambient temperatures (often above 45°C), an NCO index of 250–300 (PIR) or 110–120 (PUR) is maintained using high-functionality PMDI (typical functionality 2.65–2.75, NCO content 30.5–32.0 wt%) combined with aromatic polyester/polyether polyols (hydroxyl value 350–450 mg KOH/g). Shipments are executed in 250 kg steel drums (16–20 MT / 20ft FCL) or ISO Tank containers (22–24 MT) with UN 2078 Class 6.1 dangerous goods export documentation, SABER / SASO document support and batch COA traceability.
1. Direct Overview: Sourcing Polyurethane Raw Materials for Middle East Extreme Climates
Polymeric MDI (PMDI, CAS 9016-87-9) and high-functionality rigid polyether/polyester polyols are the primary chemical feedstocks for continuous PIR and PUR insulation panel production. In Gulf climates reaching 50°C, formulations require strict NCO index control (250-300 for PIR; 110-120 for PUR) to achieve dimensional stability and Class B1/B2 fire resistance. DOBO Chemical supplies Wanhua-sourced PM200 and custom rigid polyols from Ningbo Port to Dammam and Jeddah, with batch COA traceability, SABER documentation support and ISO Tank logistics.
2. Technical Specifications & Typical Certificate of Analysis (COA)
Consistent isocyanate functionality and polyol hydroxyl value are essential to prevent cell collapse, voids, and blistering during high-speed continuous lamination lines.
Table 1: Typical COA Specifications — Wannate PM200 vs. Standard PMDI Grades
| Parameter / Property | Standard Specification | Wannate PM200 Typical Value | Test Method / Standard |
|---|---|---|---|
| Chemical Name | Polymethylene Polyphenylene Isocyanate | Polymeric MDI | IUPAC / CAS Registry |
| CAS Number | 9016-87-9 | 9016-87-9 | CAS Database |
| NCO Content (%) | 30.5 - 32.0 | 31.2 - 31.8 | ASTM D5155 |
| Viscosity @ 25°C (mPa·s) | 150 - 250 | 180 - 220 | ASTM D4878 |
| Average Functionality (fn) | 2.6 - 2.9 | 2.7 | Calculation / GPC |
| Specific Gravity @ 25°C (g/cm³) | 1.22 - 1.25 | 1.23 | ASTM D1875 |
| Acidity (as HCl, %) | ≤ 0.05 | 0.02 | ASTM D1638 |
| Hydrolyzable Chlorine (%) | ≤ 0.20 | 0.08 | ASTM D4663 |
| Flash Point (°C) | ≥ 200 | 215 | ASTM D93 (Closed Cup) |
| Appearance | Dark brown viscous liquid | Dark brown viscous liquid | Visual Inspection |
Table 2: Rigid Polyol System for Continuous PIR Panel Production
| Polyol Grade & Type | Hydroxyl Value (mg KOH/g) | Functionality (fn) | Viscosity @ 25°C (mPa·s) | Primary Application Field |
|---|---|---|---|---|
| DOBOPOL-R4110 (Sucrose/Glycerol Base) | 410 - 450 | 4.3 | 3,500 - 5,500 | Discontinuous panels, cold storage doors |
| DOBOPOL-PIR300 (Aromatic Polyester) | 280 - 320 | 2.0 - 2.2 | 2,000 - 3,500 | High fire-retardant continuous PIR panels |
| DOBOPOL-R480 (Sorbitol Initiated) | 460 - 500 | 5.5 | 6,000 - 8,000 | Ultra-low thermal conductivity roof boards |
3. Engineering Formulation & NCO Index Calculation for High-Temperature Climates
In extreme ambient temperatures (Saudi Arabia summer conditions), formulation reactivity must be adjusted using latent catalysts and accurate NCO stoichiometry.
Theoretical Isocyanate Mass Calculation Formula
The required mass of Polymeric MDI per 100 parts by weight of polyol blend is determined by:
Mass of PMDI = [ ( Polyol Blend Hydroxyl Value / 56100 ) + ( Water Content (pbw) x 2 / 18.015 ) ] x ( 42.02 / (NCO% / 100) ) x NCO IndexOperating Guidelines for Saudi PIR Lines
- PIR Index Range: I(NCO) = 250 - 300. High isocyanurate trimerization increases char formation, a route formulators use when targeting Saudi Civil Defense and ASTM E84 Class A flame-spread performance; final results depend on the complete formulation and panel construction.
- Blowing Agent Strategy: Formulations are optimized for Cyclopentane (c-pentane) or HFC-245fa / HFO-1233zd liquid blowing systems to balance insulation performance (λ ≤ 0.020 W/(m·K)) and dimensional stability.
- Storage Temperature Management: MDI drums must be kept between 15°C and 30°C. Below 15°C, dimerization occurs; above 40°C, insoluble uretidione and biuret precipitates form.
4. Packaging, Dangerous Goods Shipping (UN 2078) & Saudi Logistics
Polymeric MDI is classified under international maritime regulations as UN 2078 / Class 6.1 Toxic Substance (or non-hazardous depending on monomeric MDI ratio and port-specific guidelines). Rigid polyols are shipped as non-regulated chemical cargo.
Export Packaging & Container Options
250 kg Steel Drums
80 drums per 20ft FCL (20.0 MT Net Payload)
1,250 kg Composite IBC Totes
16-18 IBCs per 20ft FCL (20.0-22.5 MT Net)
24,000-Liter Heated ISO Tank Containers
21.0-24.0 MT Bulk Shipment
Saudi Customs & SABER Certification Workflow
- SABER Platform Registration: DOBO Chemical issues factory ISO 9001 certificates, test reports, and factory audits required to obtain the SABER Certificate of Conformity (PCoC / SCoC).
- Typical transit time from Ningbo Port (varies by carrier and sailing schedule):
- Dammam (King Abdulaziz Port): typically 16 - 20 days (direct ocean service).
- Jeddah Islamic Port: typically 18 - 22 days.
- Riyadh Dry Port: arranged via bonded rail clearance from Dammam.

5. Frequently Asked Questions (FAQ) for Saudi Importers
6. Technical Review & Verification
- Technical review: DOBO Chemical Applied Polymer Lab (formulation team).
- Quality documentation: ISO 9001:2015 supply chain; REACH SVHC statement and RoHS documentation available on request.
- Direct export inquiries: sales@dobochemical.com | +86 15824288686 | https://dobochemical.com
Get a CIF Dammam / Jeddah Quote
Share your PM200 and rigid polyol volumes and packaging preference and our team will return indicative pricing, MOQ and lead time — with CIF Dammam, Jeddah and Riyadh arrangements.
