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Polyether Polyols & Prepolymers for CASE Applications (Coatings, Adhesives, Sealants & Elastomers): Sourcing Guide to Santos, Brazil (2026)

A practical procurement guide for Brazilian and Mercosur buyers — PPG 1000/2000/3000 specifications, hydroxyl value calculation, application matrix, packaging formats and Santos import logistics.

Published 2026-10-26•Approx. 12 min read

Target Audience: Coatings, adhesives, sealants and cast elastomer producers in Brazil and Mercosur.

Key Entities & CAS: Polyether Polyols (PPG 1000 / 2000 / 3000), MDI (CAS 9016-87-9) and TDI (CAS 584-84-9) prepolymers, Polyester CPU prepolymers.

Target Ports: Santos, Paranaguá, Itajaí (Brazil).

Target Keywords: polyether polyol CASE Brazil, PPG 2000 polyol supplier Santos, PU elastomer prepolymer China, polyurethane sealant polyol, hydroxyl value equivalent weight formula.

Quick Summary for Coatings, Adhesives, Sealants & Elastomer Producers

CASE refers to Coatings, Adhesives, Sealants and Elastomers. PPG 1000, 2000 and 3000 are common difunctional polyether polyols with hydroxyl values of approximately 112 / 56 / 37 mg KOH/g respectively, a functionality of 2.0 and a water content of ≤ 0.05%. They are used in cast PU elastomers, 2K PU coatings and waterproofing membranes, 1K / 2K sealants and adhesives, and as soft segments and toughening components. Ocean transit from Ningbo to Santos, Brazil typically takes 28 to 34 days, depending on carrier and sailing schedule. We supply 200 kg steel drums, 1,000 kg IBC totes and ISO Tanks, each shipment accompanied by a batch COA, TDS and SDS.

1. Direct Overview

CASE formulations select polyether polyols on the basis of molecular weight, functionality and water content. Higher molecular weight grades such as PPG 3000 deliver lower hardness and greater flexibility, while PPG 1000 offers higher reactivity and hardness potential. Strict water content control (≤ 0.05%) keeps the NCO stoichiometry predictable and limits CO2 side reactions and bubbles. In Brazil, local producers of coatings, sealants, rollers and sealing parts commonly build 2K coating and waterproofing systems around PPG 1000 / 2000 blends, formulate 1K / 2K sealants and adhesives with PPG 2000 / 3000, and cast elastomer rollers, wheels and seals using PPG 1000 / 2000 combined with MDI or TDI prepolymers. DOBO Chemical supplies these grades from Ningbo Port to Santos with batch COA traceability and consistent lot-to-lot quality.

2. Typical Specifications: PPG 1000 / 2000 / 3000

Consistent hydroxyl value, viscosity and water content are essential to reproducible NCO stoichiometry and stable processing in coatings, sealants and cast elastomer lines.

ParameterPPG 1000PPG 2000PPG 3000Notes / Method
Hydroxyl value (mg KOH/g)112 ± 556 ± 337.3 ± 2ASTM D4274
Equivalent weight (g/eq)≈ 501≈ 1,002≈ 1,50456,100 ÷ hydroxyl value
Functionality2.02.02.0Nominal
Molecular weight (approx.)1,0002,0003,000Calculated
Viscosity @ 25°C (mPa·s)150–250280–400450–650ASTM D4878
Water content (%)≤ 0.05≤ 0.05≤ 0.05ASTM E203 (Karl Fischer)
AppearanceClear, colourless to pale yellow liquidClear, colourless to pale yellow liquidClear, colourless to pale yellow liquidVisual

3. CASE Application Matrix

The table below maps common CASE end-uses to recommended PPG grades, typical NCO index ranges and the key property drivers for each system.

ApplicationRecommended gradeTypical NCO indexKey property drivers
Cast PU elastomers (rollers, wheels, seals)PPG 1000 / 2000 with MDI or TDI prepolymer100–105Hardness, tear strength, compression set
2K PU coatings & waterproofing membranesPPG 1000 / 2000 blends≈ 105Flexibility, adhesion, hydrolysis resistance
1K / 2K PU sealants & adhesivesPPG 2000 / 3000105–110Elongation, tack, open time
Flexibilisers & soft segmentsPPG 3000 (or PTMEG alternatives)100–105Low hardness, low-temperature flexibility

4. Formulation Formulas

The following standard calculations support CASE formulation work, covering hydroxyl value conversion, isocyanate demand and prepolymer free NCO estimation.

Equivalent weight (g/eq) = 56,100 / Hydroxyl value (mg KOH/g)

This converts a measured hydroxyl value into an equivalent weight, the basis for all NCO stoichiometry and for comparing 1000 / 2000 / 3000 grade polyols on a reactive basis.

Mass of MDI = [ ( Blend hydroxyl value / 56,100 ) + ( Water content (pbw) x 2 / 18.015 ) ] x ( 42.02 / (NCO% / 100) ) x NCO index

This estimates the MDI mass required per 100 parts of polyol blend, accounting for both the hydroxyl content and the water present in the system, adjusted by the isocyanate NCO content and the target index.

%NCO_free = [ ( MDI pbw x NCO%_MDI / 100 ) - ( 42.02 x Polyol pbw x Hydroxyl value / 56,100 ) ] / Total pbw x 100

This estimates the free NCO content of a prepolymer after the reaction between the polyol and the isocyanate, used to verify prepolymer specification and subsequent chain extension or curing ratios.

5. Packaging, Documentation & Transit to Santos

  • Packaging: 200 kg steel drums (80 drums / 20ft FCL), 1,000 kg IBC totes, 24,000 L ISO tanks for bulk.
  • Typical ocean transit from Ningbo to Santos: 28–34 days (varies by carrier and sailing schedule); Paranaguá and Itajaí routed via transshipment.
  • Documents per shipment: batch COA, TDS, SDS, commercial invoice, packing list, certificate of origin.
  • Import compliance: importers should confirm current Brazilian import requirements and NCM classification with their customs broker.
Steel drums and IBC totes of polyether polyol ready for export

6. Frequently Asked Questions

Get a CASE Polyol Quote

Share your PPG grade, volume and packaging preference and our team will return indicative pricing, MOQ and lead time — with CIF Santos, Paranaguá and Itajaí arrangements.

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